171979-19-4Relevant academic research and scientific papers
Highly isotactic optically active methacrylate polymers by free radical cyclopolymerization
Zheng, Shiying,Sogah, Dotsevi Y.
, p. 15469 - 15485 (1997)
Isospecific free radical cyclopolymerization of tartrate-based monomers gives polymers with very high optical rotations. Circular dichroism and polarimetric measurements suggest the polymers are rigid and ordered. Their high resistance to solvolysis suggests potential applications in chiral chromatography.
Synthesis of mono- and diunsaturated esters of TADDOL
Gerbino, Dario C.,Mandolesi, Sandra D.,Koll, Liliana C.,Podesta, Julio C.
, p. 2491 - 2496 (2007/10/03)
The synthesis of fourteen new mono- and diesters of (4R,5R)-2,2-dimethyl- α,α,α′,α′-tetraphenyl-1,3-dioxolane-4, 5-dimethanol (TADDOL) is reported. This study shows that esterifications of TADDOL (1) with acid chlorides, derived from normal and α,β- unsat
