17203-28-0Relevant academic research and scientific papers
Palladium-catalyzed oxidative cross-coupling reaction of arylboronic acids with diazoesters for stereoselective synthesis of (E)-α,β- diarylacrylates
Tsoi, Yuk-Tai,Zhou, Zhongyuan,Chan, Albert S. C.,Yu, Wing-Yiu
supporting information; experimental part, p. 4506 - 4509 (2010/12/25)
A Pd-catalyzed oxidative cross-coupling reaction of arylboronic acids with α-diazoesters was achieved using molecular oxygen as the sole reoxidant, and E-α,β-diarylacrylates were obtained in good yields and >20:1 E-to-Z selectivity.
First synthesis of poly(acylmethylene)s via palladium-mediated polymerization of diazoketones
Ihara, Eiji,Fujioka, Masayasu,Haida, Nobuyuki,Itoh, Tomomichi,Inoue, Kenzo
, p. 2101 - 2108 (2007/10/03)
Palladium-mediated polymerization of diazoketones (1a, 2a, 3a, 4a, and 6a) proceeded to give poly(acylmethylene)s (1b, 2b, 3b, 4b, and 6b), in which all of the main chain carbons had acyl groups. The structures of the novel polymers were characterized by
