172164-35-1Relevant academic research and scientific papers
Synthesis of Fluorophenyl Derivatives of Iron, Molybdenum and Tungsten via B(C6F5)3 and Unusual Carbon-Fluorine Bond Reactions
Chernega, Alexander N.,Graham, Andrew J.,Green, Malcolm L. H.,Haggitt, Jane,Lloyd, Julian,et al.
, p. 2293 - 2304 (2007/10/03)
The reactions between B(C6F5)3 and (η-C5H5)(CO)> 1 which reacts with the donor molecules L = PMe3, PPh3 or t-BuNC giving (η-C5H5)L>*.Likewise (η-C5H5)>2(μ-dppe)>* was formed from 1 and Ph2P(CH2)2PPh2 (dppe).The formation of the compound where L = PMe3 is shown to proceed via initial formation of (η-C5H5)(CO)(PMe3)>*.The reaction between B(C6F5)3 and (M = Mo or W) gave the compounds (η-C5H5)(CO)2>.The compounds (η-C5H5)(CO)2>* (M = Mo or W) where X = H were prepared from the compounds where X = F via unusual C-F bond-activation reactions.The compound (η-C5H5)(PMe3)> was prepared by photolysis of a mixture of (η-C5H5)(CO)> and PMe3.The asterisk indicates the crystal structure has been determined.
An Unexpected Reaction Between B(C6F5)3 and 5-C5H5)(CO)2Me> Gives Me)>(η5-C5H5)(CO)>
Green, Malcolm L. H.,Haggitt, Jane,Mehnert, Christian P.
, p. 1853 - 1854 (2007/10/02)
The reaction between B(C6F5)3 and 5-C5H5)(CO)2Me> gives the unexpected product Me)>(η5-C5H5)(CO)>, which reacts with the donor molecules L, where L = PMe3, PPh3, or ButNC, giving cycloFe-?-
