172326-99-7

Upstream product

• 172326-96-4 (2S,3S)-1-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethoxymethyl)-hex-5-en-3-ol 
• 172326-97-5 (S)-1-<(tert-Butyldimethylsilyl)oxy>-2-<<<(p-methoxybenzyl)oxy>methoxy>methyl>-5-hexen-3-on 
• 152669-29-9 (S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethoxymethyl)-propionaldehyde 
• 172326-98-6 1-[(2S,3S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-triisopropylsilanyloxy-hex-5-enyloxymethoxymethyl]-4-methoxy-benzene 

Downstream Products

• 172327-00-3 (2R,3S)-2-(4-Methoxy-benzyloxymethoxymethyl)-3-triisopropylsilanyloxy-hex-5-enal 

Relevant academic research and scientific papers

Highly Versatile Stereoselective Synthesis of All Eight Stereoisomers of Branched-Chain Triols Starting from Asymmetrized Bis(hydroxymethyl)acetaldehydes (BHYMA)

All possible stereoisomers of triols of general formula 5 (R1=allyl, R2=Me or allyl) have been synthesized stereoselectively starting from asymmetrized bis(hydroxymethyl)acetaldehyde (BHYMA), a novel chiral building block prepared through a chemoenzymatic methodology.This goal was realized through a sequence of protecting group-controlled nucleophilic additions and/or reductions performed on two side arms of this versatile building block.