172361-08-9

Upstream product

• 172360-96-2 2-(Trimethylsilyl)ethyl 2,3,6-tri-O-acetyl-4-O-<2-O-acetyl-3-deoxy-6-O-(p-methoxybenzoyl)-β-D-xylo-hexopyranosyl>-β-D-glucopyranoside 
• 160533-98-2 2-(trimethylsilyl)ethyl 4-O-(4,6-O-p-methoxybenzylidene-β-D-galactopyranosyl)-β-D-glucopyranoside 
• 108-24-7 acetic anhydride 
• 172361-07-8 2-(Trimethylsilyl)ethyl 2,3,6-tri-O-acetyl-4-O-<2-O-acetyl-3-deoxy-6-O-(p-methoxybenzoyl)-4-O-(α-D-galactopyranosyl)-β-D-xylo-hexopyranosyl>-β-D-glucopyranoside 

Downstream Products

• 172361-20-5 2,3,6-Tri-O-acetyl-4-O-<2-O-acetyl-3-deoxy-6-O-(p-methoxybenzoyl)-4-O-(2,3,4,6-tetra-O-acetyl-α-D-galactopyranosyl)-β-D-xylo-hexopyranosyl>-β-D-glucopyranose 

Relevant academic research and scientific papers

Synthesis of Double-Chain Bis-sulfone Neoglycolipids of the 2'-, 3'-, and 6'-Deoxyglobotrioses

Partially protected 2-(trimethylsilyl)ethyl deoxylactosides (deoxygenated in the 2-, 3-, and 6-positions of the galactose unit) were synthesized via various routes and glycosylated with galactosyl donors to give the corresponding deoxytrisaccharides.Removal of the protecting groups gave the 2-(trimethylsilyl)ethyl 2'-, 3'-, and 6'-deoxyglobotriosides.Transformation of the protected trisaccharides into trichloroacetimidates, via the corresponding hemiacetals, proceeded in 86 - 96percent overall yield.Glycosylation of 3-(hexadecylsulfonyl)-2-propanol with the trisaccharidic trichloroacetimidates, in 37 - 68percent yield, followed by removal of protecting groups, gave the title neoglycolipids.