172374-61-7

Basic information

• Product Name: ReCl(CO)3(C₈H₄N₄C₁₂H₁₀)
• CAS NO: 172374-61-7
• Molecular Weight: 616.049
• Mol File: 172374-61-7.mol

Chemical Properties

• CAS DataBase Reference: ReCl(CO)3(C₈H₄N₄C₁₂H₁₀)(CAS DataBase Reference)
• NIST Chemistry Reference: ReCl(CO)3(C₈H₄N₄C₁₂H₁₀)(172374-61-7)
• EPA Substance Registry System: ReCl(CO)3(C₈H₄N₄C₁₂H₁₀)(172374-61-7)

Safety Data

• Hazardous Substances Data: 172374-61-7(Hazardous Substances Data)

Upstream product

• 14099-01-5 rhenium(I) pentacarbonyl chloride 
• 1046-56-6 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine 

Relevant articles and documents

Synthesis and characterization of [ReCl(CO)3(L)] [L = 5,6-diphenyl-3-(2-pyridyl)-1,2,4-triazine (dppt) or 3,5,6-trl(2-pyridyl)-1,2,4-triazine (tpt)] and the bidentate coordination of the metalloligand [ReCl(CO)3(tpt)] to [M(hfac)2] (M = Mn, Fe, Co, Ni, Cu, Zn ; hfac = hexafluoroacetylacetonate ion)

The synthesis and characterization of the novel mononuclear species [ReCl(CO)3(L)], where L is 5,6-diphenyl-3-(2-pyridyl)-1.2.4-triazine (dppt) or 3,5,6-tri(2-pyridyl)-1,2,4-triazine (tpt), is reported. The coordination mode of the dppt and tpt ligands to the ReCl(CO)3 fragment apparently occurs through a pyridyl nitrogen and a triazine nitrogen. In addition, the tpt based monomer [ReCl(CO)3(tpt)] behaves as a bidentate metalloligand, reacting with the [M(hfac)2] (M = Mn, Fe, Co, Ni, Cu, Zn; hfac = hexafluoroacetylacetonate ion) complexes to produce the heterobimetallic substances [(CO)3ClRe(tpt)M(hfac)2]. In these Re - tpt - M complexes the tpt - M binding is atypical, since only the two free pyridyl nitrogen atoms of the chelating [ReCl(CO)3(tpt)] complex are involved. The new compounds were characterized by IR, 1H NMR and electronic spectroscopy, electrochemical and magnetic moment measurements.