172418-32-5

Basic information

• Product Name: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)
• Synonyms: cataCXium(R) C, trans-Di(μ-acetato)bis[o-(di-o-tolyl-phosphino)benzyl]dipalladium(II);trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium (II), 97+% [cataCXium C];trans-Di-^m-acetatobis[2-(di-o-tolylphosphino)benzyl]dipalladium(II), 94%;trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II), 97+%;trans-Bis(acetato)bis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium(II);trans-Bis(acetato)bis[2-[bis(2-Methylphenyl)phosphiNA]benzyl]dipalladiuM(II);trans-Bis(acetato)bis[2-[bis(2;trans-Di-μ-acetatobis[2-[bis(2-methylphenyl)phosphino]benzyl]dipalladium
• CAS NO: 172418-32-5
• Molecular Formula: C₄₆H₄₆O₄P₂Pd₂
• Molecular Weight: 937.65
• Product Categories: metal-phosphine complexes;Pd
• Mol File: 172418-32-5.mol
• Article Data: 1

Chemical Properties

• Melting Point: 230°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: yellow/crystal
• Density: g/cm³
• Storage Temp.: Inert atmosphere,Room Temperature
• CAS DataBase Reference: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)(CAS DataBase Reference)
• NIST Chemistry Reference: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)(172418-32-5)
• EPA Substance Registry System: TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)(172418-32-5)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• WGK Germany: 3
• Hazardous Substances Data: 172418-32-5(Hazardous Substances Data)

Usage

Description

TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II) is a yellow powder chemical compound, which is a type of palladium complex. It is known for its effectiveness as a catalyst in various chemical reactions, particularly in the formation of carbon-carbon and carbon-nitrogen bonds.

Uses

1. Used in Chemical Synthesis:
TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II) is used as a homogeneous catalyst for carbon-carbon bond forming reactions such as the Heck and Suzuki reactions. It facilitates the formation of these bonds, which are crucial in the synthesis of various organic compounds.
2. Used in Pharmaceutical Industry:
In the pharmaceutical industry, TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II) is used as a catalyst for C-C and C-N cross-coupling reactions. These reactions are essential in the synthesis of complex organic molecules, including those with potential pharmaceutical applications.
3. Used in Collaboration with Solvias AG:
TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II) is also used in collaboration with Solvias AG, a company specializing in the development of innovative chemical processes. The compound's catalytic properties are utilized to enhance the efficiency and selectivity of various chemical reactions in their processes.

Reaction

Heck olefination of haloarenes.

InChI:InChI=1/2C21H20P.2C2H4O2.2Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;2*1-2(3)4;;/h2*4-15H,1H2,2-3H3;2*2H,1H3;;/q;;2*-2;2*+1/p+2/rC46H50O4P2Pd2/c1-33-19-7-13-25-41(33)51(42-26-14-8-20-34(42)2)45-29-17-11-23-39(45)31-53(51)47-37(5)49-54(50-38(6)48-53)32-40-24-12-18-30-46(40)52(54,43-27-15-9-21-35(43)3)44-28-16-10-22-36(44)4/h7-30,37-38,51-52H,31-32H2,1-6H3

Upstream product

• 3375-31-3 palladium diacetate 
• 6163-58-2 tris-(o-tolyl)phosphine 

Downstream Products

• 475578-46-2 [(Pd(CH2C6H4P(o-tolyl)2-κC,P)(μ-pyrazole))2] 
• 475578-47-3 [(Pd(CH2C6H4P(o-tolyl)2-κC,P)(μ-4-methylpyrazole))2] 
• 183862-94-4 [Pd(OCOCH₃)(HN(C₂H₅)2)(C₂₁H₂₀P)] 
• 7440-05-3 palladium 
• 69861-71-8 bis(tri-ortho-tolylphosphine)palladium⁽⁰⁾ 
• 1199828-99-3 methyl 1-(benzyloxycarbonylamino)-2,3-dihydro-1H-indene-5-carboxylate 

Relevant articles and documents

Palladacycles as structurally defined catalysts for the heck olefination of chloro- and bromoarenes

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