172427-39-3

Upstream product

• 172427-44-0 (E)-3-{(2S,3S)-3-[(2S,3S,4S,5R,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-tetrahydro-pyran-2-ylmethyl]-oxiranyl}-acrylic acid methyl ester 
• 172427-45-1 (E)-3-[(2S,3S,4aS,6R,7R,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-7-methoxy-6-methoxymethyl-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester 
• 172427-42-8 (E)-4-[(2S,3S,4S,5R,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-tetrahydro-pyran-2-yl]-but-2-enoic acid methyl ester 
• 172427-54-2 [(2S,3S,4S,5R,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-tetrahydro-pyran-2-yl]-acetic acid ethyl ester 
• 172427-43-9 {(2S,3S)-3-[(2S,3S,4S,5R,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-tetrahydro-pyran-2-ylmethyl]-oxiranyl}-methanol 
• 172427-55-3 (E)-4-[(2S,3S,4S,5R,6R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-6-methoxymethyl-tetrahydro-pyran-2-yl]-but-2-en-1-ol 
• 172427-41-7 ((2S,3S,4S,5R,6R)-3-Allyloxy-4-benzyloxy-5-methoxy-6-methoxymethyl-tetrahydro-pyran-2-yl)-acetic acid ethyl ester 
• 172427-56-4 [(2S,3S,4aS,6R,7R,8S,8aS)-8-Benzyloxy-2-(2,2-dibromo-vinyl)-7-methoxy-6-methoxymethyl-octahydro-pyrano[3,2-b]pyran-3-yloxy]-tert-butyl-dimethyl-silane 

Downstream Products

• 172427-51-9 (2R,3R,4S,4aS,6S,7S,8aS)-4,7-Bis-benzyloxy-6-[(E)-3-((2R,3R,4S,4aS,8aS)-4-benzyloxy-3-methoxymethoxy-octahydro-pyrano[3,2-b]pyran-2-yl)-propenyl]-3-methoxy-2-methoxymethyl-octahydro-pyrano[3,2-b]pyran 
• 172427-50-8 C₄₄H₆₄O₁₁Si 

Relevant academic research and scientific papers

Stereochemical assignment of the C35-C39 acyclic linkage in maitotoxin: Completion of stereochemical determination of C15-C134

The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in 1H and 13C NMR spectra. This result completed stereochemical assignments of the whole molecule except for side chains.