172427-46-2

Upstream product

• 81972-19-2 1-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-2-propene 

Downstream Products

• 172585-94-3 (2R,4aR,8aR,9S,9aS,10aS)-2-Phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-9-ol 
• 172427-48-4 (2R,4aR,8aR,9R,9aS,10aS)-2-Phenyl-octahydro-1,3,8,10-tetraoxa-anthracen-9-ol 
• 172427-51-9 (2R,3R,4S,4aS,6S,7S,8aS)-4,7-Bis-benzyloxy-6-[(E)-3-((2R,3R,4S,4aS,8aS)-4-benzyloxy-3-methoxymethoxy-octahydro-pyrano[3,2-b]pyran-2-yl)-propenyl]-3-methoxy-2-methoxymethyl-octahydro-pyrano[3,2-b]pyran 
• 172427-50-8 C₄₄H₆₄O₁₁Si 
• 172427-47-3 Toluene-4-sulfonic acid 3-((2R,4aR,6S,7R,8R,8aS)-7,8-dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-propyl ester 
• 172427-40-6 Trifluoro-methanesulfonic acid (2R,3R,4S,4aS,8aS)-4-benzyloxy-3-methoxymethoxy-octahydro-pyrano[3,2-b]pyran-2-ylmethyl ester 
• 172427-49-5 (2R,4aR,8aS,9S,9aR,10aS)-9-Benzyloxy-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracene 

Relevant academic research and scientific papers

Stereochemical assignment of the C35-C39 acyclic linkage in maitotoxin: Completion of stereochemical determination of C15-C134

The relative configuration of carbons within the C35-C39 acyclic linkage of maitotoxin (MTX) was assigned by synthesis of stereodefined model compound 1 and its comparison with MTX in 1H and 13C NMR spectra. This result completed stereochemical assignments of the whole molecule except for side chains.