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172470-89-2

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172470-89-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 172470-89-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,2,4,7 and 0 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 172470-89:
(8*1)+(7*7)+(6*2)+(5*4)+(4*7)+(3*0)+(2*8)+(1*9)=142
142 % 10 = 2
So 172470-89-2 is a valid CAS Registry Number.

172470-89-2Downstream Products

172470-89-2Relevant articles and documents

A versatile method for the preparation of substituted 1,2,3,4-tetrahydroquinolines

Katritzky,Rachwal,Rachwal

, p. 7631 - 7640 (2007/10/03)

N-Alkyl-N-aryl-1H-benzotriazole-1-methanamines 1 react with acetaldehyde to give 4-(benzotriazol-1-yl)-1,2,3,4-tetrahydroquinolines 11 in good yields along with minor amounts of diamines 12. Reactions of 1 with higher enolizable aldehydes R1CH2CHO lead to 4-(benzotriazol-1-yl)tetrahydroquinolines with an R1 substituent at C-3 (17, 18). Condensation of N-methylaniline with two molecules of aldehyde RCH2CHO and one molecule of benzotriazole produces 4-(benzotriazol-1-yl)-1,2,3,4-tetrahydroquinolines 34 bearing an R substituent at C-3 and RCH2 on C-2. In all of these products, the benzotriazol-1-yl moiety can be replaced by a hydrogen atom (by reduction with lithium aluminum hydride) or by an alkyl or aryl group (by reaction with a Grignard reagent). Treatment of 11 with sodium alkoxides leads to 4-alkoxy-1,2,3,4-tetrahydroquinolines 10. Elimination of a molecule of nitrogen from the benzotriazole system of 4-(benzotriazol-1-yl)-1,2,3,4-tetrahydroquinolines 17, 18, and 35 by sodium hydride produces the corresponding 4-(phenylamino)1,2-dihydroquinolines 26 (R1 = alkyl) or 4-(phenylimino)-1,2,3,4-tetrahydroquinolines 27 and 38 (R = Ph), depending on the nature of the substituents at C-3 and the workup conditions.

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