172481-14-0Relevant articles and documents
Synthesis and imido-group exchange reactions of tert-butylimidotitaniuni complexes
Blake, Alexander J.,Collier, Philip E.,Dunn, Simon C.,Li, Wan-Sheung,Mountford, Philip,Shishkin, Oleg V.
, p. 1549 - 1558 (1997)
Treatment of TiCl4 with ButNH2 (6 equivalents) followed by addition of bpy (2 equivalents, 4-/er/-butylpyridine) or pyridine (py) (2 or 4 equivalents) afforded the five- or six-co-ordinate /erf-butylimido complexes [ri(NBu
Exchange of Organoimido Groups at a Mononuclear Titanium Centre and a Crystallographic Evaluation of the Relative Structural Influences of the NBut, NC6H4Me-4 and NC6H4NO2-4 Ligands
Collier, Philip E.,Dunn, Simon C.,Mountford, Philip,Shishkin, Oleg V.,Swallow, Daniel
, p. 3743 - 3746 (2007/10/03)
The tert-butylimido complex t)Cl2(py)3> 1a (py = pyridine) undergoes exchange reactions of the NBut ligand with arylamines RNH2 to form the arylimido derivatives (R = C6H4Me-4 1b, C6H4NO2-4 1c or C6H3Me2-2,6 1d); comparison of the crystal structures of 1a-1c gave a direct evaluation of N-substituent effects in d0, six-co-ordinated organoimido complexes.