172483-29-3

Upstream product

• 172483-27-1 N-[(1R,2R,5R,6S)-2-(1,3-benzodioxol-5-yl)-5,6-(isopropylidenedioxy)cyclohex-3-en-1-yl]-N-(methoxycarbonyl)-4-methylbenzenesulfonamide 
• 172483-26-0 N-((3aS,4R,5R,7aR)-2,2-Dimethyl-3a,4,5,7a-tetrahydro-[5,5']bi[benzo[1,3]dioxolyl]-4-yl)-4-methyl-benzenesulfonamide 
• 172483-33-9 (1aR,3aS,6aS,6bR)-3-Bromo-5,5-dimethyl-1a,3a,6a,6b-tetrahydro-4,6-dioxa-1-aza-cyclopropa[e]indene-1-carboxylic acid methyl ester 
• 183902-27-4 (3aS,4S,5R,7aS)-5-Azido-7-bromo-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-4-ol 
• 172483-34-0 methyl (1R,4R,5S,6R)-4,5-(isopropylidenedioxy)-7-azabicyclo[4.1.0]hept-2-ene-7-carboxylate 
• 183674-17-1 (1R,2S,5S,6R)-3,6-dibromo-1,2-O-isopropylidenecyclohex-3-ene-1,2,5-triol 
• 163082-04-0 (1R,4S,5S,6R)-3-bromo-4,5-(isopropylidenedioxy)-7-(4'-methylphenylsulfonyl)-7-azabicyclo<4.1.0>hept-2-ene 
• 160309-18-2 (1R,4R,5S,6R)-4,5-(isopropylidenedioxy)-7-(4'-methylphenylsulfonyl)-7-azabicyclo<4.1.0>hept-2-ene 
• 130669-75-9 (3aS,7aS)-4-bromo-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole 
• 67451-62-1 cis-(1S,2S)-1,2-dihydroxy-3-bromocyclohexa-3,5-diene 
• 172483-28-2 ((3aS,4R,5R,7aR)-2,2-Dimethyl-3a,4,5,7a-tetrahydro-[5,5']bi[benzo[1,3]dioxolyl]-4-yl)-carbamic acid methyl ester 

Downstream Products

• 172483-32-8 Acetic acid (1R,2S,3S,4S,5R,6R)-2,3,4-triacetoxy-6-benzo[1,3]dioxol-5-yl-5-methoxycarbonylamino-cyclohexyl ester 
• 172483-31-7 ((1R,2R,3R,4S,5S,6S)-2-Benzo[1,3]dioxol-5-yl-3,4,5,6-tetrahydroxy-cyclohexyl)-carbamic acid methyl ester 
• 713496-66-3 Acetic acid (1S,2R,3R,6R)-6-acetoxy-3-benzo[1,3]dioxol-5-yl-2-methoxycarbonylamino-cyclohexyl ester 
• 713496-73-2 Acetic acid (1S,2R,5R,6R)-2-acetoxy-5-benzo[1,3]dioxol-5-yl-6-methoxycarbonylamino-cyclohex-3-enyl ester 

Relevant academic research and scientific papers

Toluene dioxygenase-mediated cis-dihydroxylation of aromatics in enantioselective synthesis. Asymmetric total syntheses of pancratistatin and 7-deoxypancratistatin, promising antitumor agents

Whole-cell biooxidation of bromobenzene with Pseudomonas putida 39D or the recombinant Escherichia coli JM109 (pDTG601) yields (1S,2S)-3-bromocyclohexa-3,5-diene-1,2-diol (9a), which is protected as the acetonide and converted to vinylaziridines 7, 15a, 6