172505-18-9

Basic information

• Product Name: Spiro[bicyclo[2.2.1]heptane-7,1-cyclopropane], 2-(1-methylethyl)-, (1alpha,2alpha,4alpha)- (9CI)
• Synonyms: Spiro[bicyclo[2.2.1]heptane-7,1-cyclopropane], 2-(1-methylethyl)-, (1alpha,2alpha,4alpha)- (9CI)
• CAS NO: 172505-18-9
• Molecular Formula: C12H20
• Molecular Weight: 164.2872
• Product Categories: ISOPROPYL
• Mol File: 172505-18-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Spiro[bicyclo[2.2.1]heptane-7,1-cyclopropane], 2-(1-methylethyl)-, (1alpha,2alpha,4alpha)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Spiro[bicyclo[2.2.1]heptane-7,1-cyclopropane], 2-(1-methylethyl)-, (1alpha,2alpha,4alpha)- (9CI)(172505-18-9)
• EPA Substance Registry System: Spiro[bicyclo[2.2.1]heptane-7,1-cyclopropane], 2-(1-methylethyl)-, (1alpha,2alpha,4alpha)- (9CI)(172505-18-9)

Safety Data

• Hazardous Substances Data: 172505-18-9(Hazardous Substances Data)

Upstream product

• 7125-50-0 spirohept-2-ene-7,1'-cyclopropane> 
• 4907-44-2 di-n-propylmagnesium 

Relevant articles and documents

Catalytic synthesis and transformations of magnesacycloalkanes 3. Cyclomagnesation of norbornenes catalyzed by Cp2ZrCl2

Catalytic cyclometallation of bicyclohept-2-ene, spirohept-2-ene-7.1'-cyclopropane> and endo-tricyclo2,6>deca-3,8-diene (dicyclopentadiene) with R2Mg (R = n-Pr, n-Bu) leading to the formation of polycyclic magnesacyclopentanes (MC) has been studied.The yield of MC and the selectivity of the reaction have been shown to depend on the ratio of starting reagents, the solvent, and temperature.The most probable scheme of the transformation studied is proposed.