172532-53-5

Upstream product

• 24850-33-7 allyltributylstanane 
• 152669-29-9 (S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxymethoxymethyl)-propionaldehyde 

Downstream Products

• 172487-98-8 (2R,3R)-2-(4-Methoxy-benzyloxymethoxymethyl)-3-triisopropylsilanyloxy-hex-5-enal 
• 172487-97-7 (2R,3R)-2-(4-Methoxy-benzyloxymethoxymethyl)-3-triisopropylsilanyloxy-hex-5-en-1-ol 

Relevant academic research and scientific papers

Highly Versatile Stereoselective Synthesis of All Eight Stereoisomers of Branched-Chain Triols Starting from Asymmetrized Bis(hydroxymethyl)acetaldehydes (BHYMA)

All possible stereoisomers of triols of general formula 5 (R1=allyl, R2=Me or allyl) have been synthesized stereoselectively starting from asymmetrized bis(hydroxymethyl)acetaldehyde (BHYMA), a novel chiral building block prepared through a chemoenzymatic methodology.This goal was realized through a sequence of protecting group-controlled nucleophilic additions and/or reductions performed on two side arms of this versatile building block.