172688-58-3

Basic information

• Product Name: N-Methoxy-N-{(1R,4S)-4-[2-oxo-1-(toluene-4-sulfonyl)-propyl]-cyclopent-2-enyl}-acetamide
• Synonyms: N-Methoxy-N-{(1R,4S)-4-[2-oxo-1-(toluene-4-sulfonyl)-propyl]-cyclopent-2-enyl}-acetamide
• CAS NO: 172688-58-3
• Molecular Weight: 365.45
• Mol File: 172688-58-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Methoxy-N-{(1R,4S)-4-[2-oxo-1-(toluene-4-sulfonyl)-propyl]-cyclopent-2-enyl}-acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Methoxy-N-{(1R,4S)-4-[2-oxo-1-(toluene-4-sulfonyl)-propyl]-cyclopent-2-enyl}-acetamide(172688-58-3)
• EPA Substance Registry System: N-Methoxy-N-{(1R,4S)-4-[2-oxo-1-(toluene-4-sulfonyl)-propyl]-cyclopent-2-enyl}-acetamide(172688-58-3)

Safety Data

• Hazardous Substances Data: 172688-58-3(Hazardous Substances Data)

Upstream product

• 172476-78-7 (R)-2,N-Dihydroxy-N-((1R,2S)-2-hydroxy-cyclopent-3-enyl)-2-phenyl-acetamide 
• 5366-49-4 4-toluenesulfonylacetone 
• 172688-57-2 Acetic acid (1S,5R)-5-[((R)-2-acetoxy-2-phenyl-acetyl)-methoxy-amino]-cyclopent-2-enyl ester 

Relevant articles and documents

Stereoselective cycloadditions of chiral acyl-nitroso compounds; Palladium(0) catalyzed allylic displacement with concomitant loss of the chiral auxiliary

The methylated diacetate 4, derived from the readily available hydroxamic acid 1, undergoes Pd0 catalyzed nucleophilic allylic displacement under conditions which also result in the removal of the chiral auxiliary and its replacement with an easily removed acetyl group.