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172823-06-2

(Sp)-O-(+)-menthyl-H-phosphinate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 172823-06-2 Structure

  • Basic information

    1. Product Name: (Sp)-O-(+)-menthyl-H-phosphinate
    2. Synonyms: (Sp)-O-(+)-menthyl-H-phosphinate
    3. CAS NO:172823-06-2
    4. Molecular Formula:
    5. Molecular Weight: 280.347
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 172823-06-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (Sp)-O-(+)-menthyl-H-phosphinate(CAS DataBase Reference)
    10. NIST Chemistry Reference: (Sp)-O-(+)-menthyl-H-phosphinate(172823-06-2)
    11. EPA Substance Registry System: (Sp)-O-(+)-menthyl-H-phosphinate(172823-06-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 172823-06-2(Hazardous Substances Data)

172823-06-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 172823-06-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,7,2,8,2 and 3 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 172823-06:
(8*1)+(7*7)+(6*2)+(5*8)+(4*2)+(3*3)+(2*0)+(1*6)=132
132 % 10 = 2
So 172823-06-2 is a valid CAS Registry Number.

172823-06-2Relevant articles and documents

Diastereoselective Synthesis of Adjacent P,C-Stereogenic β-N-Glycosidic Linked α-Aminophosphinates

Liu, Shuang,Li, Yuming,Yin, Zhiyu,Yu, Qiuli,Miao, Zhiwei

, p. 2481 - 2488 (2017/03/14)

The diastereoselective formation of adjacent P,C-stereogenic β-N-glycosidic linked α-aminophosphinates is developed in high yields via a phospha-Mannich reaction. The reaction was performed by employing (Rp)-O-(?)-menthyl H-phenylphosphinate and O-pivaloylated N-galactosylimine for double stereodifferentiation and BF3·Et2O as a promoter in THF. O-Pivaloylated N-galactosylphenyl imine 2 and (Rp)-O-(?)-menthyl H-phenylphosphinate 1 were converted to N-galactosyl α-aminoalkylphosphinate 3 with ratios of diastereomers up to 20:1. The synthetic method of the conversion provides a rapid access to adjacent P,C-stereogenic chiral α-aminophosphinates.

Asymmetric Suzuki-Miyaura cross-coupling for the synthesis of chiral biaryl compounds as potential monophosphine ligands

Ma, Yan-Na,Yang, Shang-Dong

supporting information, p. 6673 - 6677 (2015/04/27)

Efficient asymmetric Suzuki-Miyaura coupling reactions have been employed for the first time to synthesize chiral biaryl compounds with phosphinate groups as chiral auxiliaries. A series of functionalized chiral biaryls are thereby synthesized in excellent yields and good diastereoselectivities (up to >95:5 d.r.) and axially chiral monophosphorus ligands are obtained through further functionalizations.

Stereospecific nucleophilic substitution of optically pure H-phosphinates: A general way for the preparation of chiral P-stereogenic phosphine oxides

Xu, Qing,Zhao, Chang-Qiu,Han, Li-Biao

supporting information; experimental part, p. 12648 - 12655 (2009/05/09)

Contrary to the generally held view, it is found that the rapid epimerization of (-)-menthyl (RP)-phenylphosphinate under basic conditions is not due to the so far believed inherent stereolability of its corresponding anion but due to a reactio

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