1729-09-5

Basic information

• Product Name: Hydroperoxide, 2,4,5-triphenyl-4H-imidazol-4-yl
• CAS NO: 1729-09-5
• Molecular Formula: C21H16N2O2
• Molecular Weight: 328.37
• Mol File: 1729-09-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Hydroperoxide, 2,4,5-triphenyl-4H-imidazol-4-yl(CAS DataBase Reference)
• NIST Chemistry Reference: Hydroperoxide, 2,4,5-triphenyl-4H-imidazol-4-yl(1729-09-5)
• EPA Substance Registry System: Hydroperoxide, 2,4,5-triphenyl-4H-imidazol-4-yl(1729-09-5)

Safety Data

• Hazardous Substances Data: 1729-09-5(Hazardous Substances Data)

Upstream product

• 134-81-6 benzil 
• 484-47-9 lophine 

Downstream Products

• 102241-25-8 2,4,5-triphenyl-4-hydroxy-4H-imidazole 
• 37068-60-3 2,5,5-triphenyl-1H-imidazol-4(5H)-one 
• 16776-74-2 N,N'-dibenzoyl-benzamidine 

Relevant articles and documents

Evidence for the Formation of 1,2-Dioxetane as a High-Energy Intermediate and Possible Chemiexcitation Pathways in the Chemiluminescence of Lophine Peroxides

A kinetic study of the chemiluminescent (CL) reaction mechanism of lophine-derived hydroperoxides and silylperoxides induced by a base and fluoride, respectively, provided evidence for the formation of a 1,2-dioxetane as a high-energy intermediate (HEI) o

Heat- or singlet oxygen-generating agents and cancer treatment compositions comprising organic peroxide or chemiluminescent compound

The present invention provides a heat-generating agent or singlet oxygen-generating agent effective as a new cancer treatment agent which, unlike an anticancer agent based on an alkylating agent such as MMC, uses the action of heat and/or singlet oxygen to kill cancer cells and reduce the burden on patients. A heat- and/or singlet oxygen-generating agent or a cancer treatment agent, comprising an organic peroxide such as the peroxide of an imidazole derivative or a chemiluminescent compound such as a dioxetane compound.

Location effect of an OH group on the chemiluminescence efficiency of 4-hydroperoxy-2-(o-, m-, or p-hydroxyphenyl)-4,5-diphenyl-4H-isoimidazoles

In studying the location effect of an OH group on the chemiluminescence efficiency of 4-hydroperoxy-2-(o-, m-, or p-hydroxyphenyl)-4,5-diphenyl-4H- isoimidazoles 4, we found that the efficiency of 4a with o-OH was 0.28 times that of lophine peroxide on initiation with KOH/MeOH. When the trigger base was changed to TBAF/THF, efficiency was 530-fold in dry DMF. The efficiency of 4b with m-OH or 4c with p-OH showed no such dramatic change.