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Hydroperoxide, 2,4,5-triphenyl-4H-imidazol-4-yl, also known as 2,4,5-triphenylimidazolium hydroperoxide, is a complex organic compound with the chemical formula C25H20N2O2. It is a derivative of imidazole, a heterocyclic aromatic organic compound, and features three phenyl groups attached to the imidazole ring. Hydroperoxide, 2,4,5-triphenyl-4H-imidazol-4-yl is of interest in the field of chemistry, particularly in the study of peroxides and their applications. It is known for its potential use in oxidation reactions and as a precursor in the synthesis of various organic compounds. The presence of the hydroperoxide group (-OOH) makes it a reactive species, which can participate in a variety of chemical transformations. Due to its unique structure and reactivity, it is a subject of research in organic synthesis and may have applications in the development of new materials and chemical processes.

1729-09-5

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1729-09-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1729-09-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,2 and 9 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1729-09:
(6*1)+(5*7)+(4*2)+(3*9)+(2*0)+(1*9)=85
85 % 10 = 5
So 1729-09-5 is a valid CAS Registry Number.

1729-09-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-hydroperoxy-2,4,5-triphenylimidazole

1.2 Other means of identification

Product number -
Other names Hydroperoxide,2,4,5-triphenyl-4H-imidazol-4-yl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1729-09-5 SDS

1729-09-5Relevant academic research and scientific papers

Evidence for the Formation of 1,2-Dioxetane as a High-Energy Intermediate and Possible Chemiexcitation Pathways in the Chemiluminescence of Lophine Peroxides

Boaro, Andreia,Reis, Roberta Albino,Silva, Carolina Santana,Melo, Diêgo Ulysses,Pinto, Alexander Garreta Gon?alves Costa,Bartoloni, Fernando Heering

, p. 6633 - 6647 (2021)

A kinetic study of the chemiluminescent (CL) reaction mechanism of lophine-derived hydroperoxides and silylperoxides induced by a base and fluoride, respectively, provided evidence for the formation of a 1,2-dioxetane as a high-energy intermediate (HEI) o

An energy transfer chemiluminescent reaction of lophine peroxides

Kimura, Masaru,Akaki, Kaoru,Mishima, Yasunobu,Araki, Hiroyuki,Fukai, Takeshi

experimental part, p. 1019 - 1024 (2009/12/26)

A linear correlation existed between the absorption energy of activators (Eo-o's) and the sensitized chemiluminescence (CL) yields (φSCL's) for the CL reaction of lophine peroxides (2a and 2b), whereas a linear correlation did not exist between their oxidation potentials (Eox's) and φSCL's. Based on the finding, an energy transfer mechanism is likely rather than an electron transfer mechanism like the CIEEL mechanism.

The stereoselective thermal rearrangement of chiral lophine peroxides

Kimura, Masaru,Lu, Gonghao,Iga, Hiroshi,Tsunenaga, Mitsuru,Zhang, Zhiqiang,Hu, Zhizhi

, p. 3109 - 3113 (2008/02/03)

The thermal reaction of chiral 2-phenyl-4-(p-X-phenyl)-5-(p-Y-phenyl)-4-tert-butyldimethylsilylperoxy-4H-isoimidazoles (5b: X = CF3, Y = OMe; 5c: X = CF3, Y = F) was carried out in DMSO. The chiral 2-phenyl-5-(p-X-phenyl)-5-(p-Y-phen

Heat- or singlet oxygen-generating agents and cancer treatment compositions comprising organic peroxide or chemiluminescent compound

-

Page/Page column 6, (2008/06/13)

The present invention provides a heat-generating agent or singlet oxygen-generating agent effective as a new cancer treatment agent which, unlike an anticancer agent based on an alkylating agent such as MMC, uses the action of heat and/or singlet oxygen to kill cancer cells and reduce the burden on patients. A heat- and/or singlet oxygen-generating agent or a cancer treatment agent, comprising an organic peroxide such as the peroxide of an imidazole derivative or a chemiluminescent compound such as a dioxetane compound.

Location effect of an OH group on the chemiluminescence efficiency of 4-hydroperoxy-2-(o-, m-, or p-hydroxyphenyl)-4,5-diphenyl-4H-isoimidazoles

Tsunenaga, Mitsuru,Iga, Hiroshi,Kimura, Masaru

, p. 1877 - 1880 (2007/10/03)

In studying the location effect of an OH group on the chemiluminescence efficiency of 4-hydroperoxy-2-(o-, m-, or p-hydroxyphenyl)-4,5-diphenyl-4H- isoimidazoles 4, we found that the efficiency of 4a with o-OH was 0.28 times that of lophine peroxide on initiation with KOH/MeOH. When the trigger base was changed to TBAF/THF, efficiency was 530-fold in dry DMF. The efficiency of 4b with m-OH or 4c with p-OH showed no such dramatic change.

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