17290-68-5Relevant academic research and scientific papers
A Practical Synthesis of Rosefuran. Furans from Acetylenes and Allyl Alcohols
Trost, Barry M.,Flygare, John A.
, p. 1078 - 1082 (1994)
A new atom-economical synthetic strategy for the synthesis of furans emerges from β,γ-unsaturated ketones which are readily available from acetylenes and allyl alcohols by simple additions in the presence of a ruthenium catalyst.Dihydroxylation using cata
Reaction of Carboxonium Ions of Cyclic Acetals, IX. - Synthesis of Rosefuran and Structurally Related Terpene-like Esters, Alcohols, and Olefins
Meier, Lothar,Scharf, Hans-Dieter
, p. 731 - 740 (2007/10/02)
Thermolysis of the 4-(o-toluoyloxy)-1,3-dioxolanes 4 leads to the furans 6/7 which, via Grignard reaction, can be converted into the alcohols 8/9.Subsequent dehydratization affords the olefins 10/11, e.g. rosefuran (10a).
