172915-45-6

Basic information

• Product Name: ((C₆F₅NCH₂CH₂)3N)ReBr
• Synonyms: ((C₆F₅NCH₂CH₂)3N)ReBr
• CAS NO: 172915-45-6
• Molecular Weight: 907.473
• Mol File: 172915-45-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((C₆F₅NCH₂CH₂)3N)ReBr(CAS DataBase Reference)
• NIST Chemistry Reference: ((C₆F₅NCH₂CH₂)3N)ReBr(172915-45-6)
• EPA Substance Registry System: ((C₆F₅NCH₂CH₂)3N)ReBr(172915-45-6)

Safety Data

• Hazardous Substances Data: 172915-45-6(Hazardous Substances Data)

Upstream product

• 75331-93-0 Ta(neopentylidene)(THF)2Br₃ 
• 122383-54-4 Ta(tetrahydrothiophene)2Br₄ 
• 155019-77-5 2,2',2''-tris<(pentafluorophenyl)amino>triethylamine 

Downstream Products

• 172915-46-7 ((C₆F₅NCH₂CH₂)3N)Re(N₂) 
• 212784-19-5 ((C₆F₅NCH₂CH₂)3N)Re(PMe₃) 
• 212784-25-3 ((C₆F₅NCH₂CH₂N)3N)Re(pyridine) 
• 172915-49-0 ((C₆F₅NCH₂CH₂)3N)Re(ethylene) 
• 212784-26-4 ((C₆F₅NCH₂CH₂N)3N)Re(tetrahydrothiophene) 
• 212784-20-8 ((C₆F₅NCH₂CH₂)3N)Re(PEt₃) 
• 212784-28-6 ((C6F5NCH2CH2N)3N)Re(η(2)-H2SiEt2) 
• 212784-18-4 ((C₆F₅NCH₂CH₂)3N)Re(PH₃) 
• 212784-21-9 ((C₆F₅NCH₂CH₂)3N)Re(P(i-Pr)3) 
• 212784-22-0 ((C₆F₅NCH₂CH₂)3N)Re(PMe₂Ph) 
• 172915-47-8 ((C₆F₅NCH₂CH₂)3N)Re(CO) 
• 212784-23-1 ((C₆F₅NCH₂CH₂)3N)Re(PMePh₂) 
• 212784-16-2 ((C₆F₅NCH₂CH₂)3N)Re(propylene) 

Relevant articles and documents

Synthesis of rhenium complexes that contain the [(C6F5NCH2CH2)3N] 3- ligand

The reaction between [Et4N]2[ReOCl5] and (C6F5NHCH2CH2)3N (H3[N3NF]) in CH3CN at room temperature in the presence of NEt3 yielded air stable, emerald green, diamagnetic [(C6F5NCH2CH2)2NCH 2CH2NHC6F5]Re(O)Cl (1). The reaction between 1 and Ta(CH-t-Bu)(THF)2Br3 gave paramagnetic [N3NF]ReBr (2). An X-ray structure of a sample of 2 showed it to be analogous to that of [N3NF]MoCl. Reduction of 2 by methyllithium (or more conveniently by Mg) in the presence of a variety of two-electron ligands gave complexes of the type [N3NF]Re(L) (L = H2, ethylene, propylene, CO, N2, phosphines, pyridine, tetrahydrothiophene, acetonitrile, or silanes). An X-ray structure of [N3NF]Re(ethylene) showed η2-ethylene to be bound in the apical "pocket" with its C-C axis lying in one of the Nax- Re-Neq planes. Protonation of the PMe3 complex gave an authentic hydrido phosphine complex, {[N3NF]Re(H)(PMe3)}+, but protonation of other phosphine complexes gave species in which coupling between H and P is relatively large (～60 Hz) and therefore that are believed to have some {[N3NF]Re(η2-HPRxH 3-x)}+ character. An X-ray study of {[N3NF]Re(H)-(PHPh2)}+ confirmed that one proton is terminally bound to phosphorus and that the phosphorus is "off-axis" in order to accommodate the "hydride" in the same plane.