17293-74-2Relevant academic research and scientific papers
Phosphorus-Nitrogen Compounds. Part 49. The Synthesis and Mechanism of Formation of 6-Chloro-5,6,7,12-tetrahydro-2,5,7,10-tetramethyldibenzo-diazaphosphocine 6-Oxide and 6-Sulphide
Demir, Tuersen,Shaw, Robert A.
, p. 1547 - 1552 (2007/10/02)
A reaction mechanism is proposed for the formation of the title compounds in the reactions between N,N-dimethyl-p-toluidine and phosphoryl and thiophosphoryl chlorides.The synthesis of 2,2'-methylenebis(p-toluidine) and 2,2'-methylenebis(N-methyl-p-toluidine) are described, as are their reactions with phosphoryl and thiophosphoryl chlorides.
Aromatic Amines and their Derivatives. Part 3. The Synthesis and Crystal Structure of 4,4'-NN'-Tetramethyl-NN'-dinitroso-2,2'-methylenedianiline
Chakrabarti, Pinakpani,Venkatesan, Kailasam,Cameron, Theodore Stanley,Demir, Tuersen,Shaw, Robert A.
, p. 206 - 211 (2007/10/02)
The synthesis of 4,4',NN'-tetramethyl-NN'-dinitroso-2,2'-methylenedianiline (1) by the route p-MeC6H4NH2 + HCHO + OH- ---> (p-MeC6H4NMe)2CH2 (7b); (7b) + acid at 70 deg C ---> 4,N-dimethyl-6-(N-methyl-p-toluidinomethyl)aniline (4b); (4b) + acid at 130 deg
