173035-75-1Relevant academic research and scientific papers
Enantioselective Synthesis of Succinic Acids and γ-Lactones via Palladium Catalysed Allylic Substitution Reactions
Dawson, Graham J.,Williams, Jonathan M. J.,Coote, Steven J.
, p. 2535 - 2546 (2007/10/03)
The palladium catalyzed reaction between non-symmetrical allyl acetates and sodiodimethylmalonate proceeds in high yields and enantioselectivities (up to 99percent ee) using a diphenylphosphinoaryl oxazoline ligand.The so-formed substitution products are transformed into enantiomerically enriched succinic acids and also into enantiomerically enriched γ-lactones.
