17321-48-1Relevant articles and documents
REACTION OF PHOSPHORUS THIOACID CHLORIDES WITH ETHYL ISOBUTYRIMIDATE HYDROCHLORIDE, PROPERTIES OF PHOSPHORYL THIOIMIDATES
Krongauz, Yu. I.,Potapova, V. V.,Sandakov, V. B.,Koroleva, T. N.,Bogomolova, L. M.
, p. 345 - 348 (2007/10/02)
Phosphorus thioacid chlorides react with ethyl isobutyrimidate with the formation of 1-ethoxy-1-methylpropylideneamidothiophosphates, which can be hydrolyzed at both C=N and P-N bonds.
1,3,2-Oxazaphospholidine-2-thiones from (+)-Norephedrine: Stereospecific Ring Opening, Possibly by an Elimination-Addition Mechanism
Hall, C.Richard,Inch, Thomas D.,Williams, Nancy E.
, p. 639 - 644 (2007/10/02)
1,3,2-Oxazaphospholidine-2-thiones derived from (+)-norephedrine react with alkoxide to give a product of kinetic control, formed by endocyclic P-O cleavage with inversion of configuration, and one of thermodynamic control, formed by endocyclic P-N cleavage also with inversion of configuration.It is suggested that the product of kinetic control is formed by an elimination-addition process involving a metaphosphorimidate intermediate, and that of thermodynamic control by a mechanism involving nucleophilic attack opposite endocyclic nitrogen.
Reactions of N'-cyano-N-phenylformamidine and carbodiimide with phosphorodithioic acid O,O-diethyl ester
Fedgenhaeuer,Moll
, p. 141 - 142 (2007/10/02)
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