173277-05-9Relevant academic research and scientific papers
Catalytic conversion of conjugated enones into optically active α-keto aziridines using chiral rare earth metal complexes
Sugihara, Hiroyasu,Daikai, Kazuhiro,Jin, Xiu Lan,Furuno, Hiroshi,Inanaga, Junji
, p. 2735 - 2739 (2007/10/03)
Optically active N-unsubstituted α-keto aziridines 2 were synthesized from conjugated enones 1 via the Sc[(R)-BNP]3-catalyzed enantioselective Michael addition of O-methylhydroxylamine followed by the La(O-i-Pr)3-catalyzed ring closu
Synthesis of 4-phenylpiperidines by tandem Wittig olefination-aza-Wittig rearrangement of 2-benzoylaziridines
Coldham, Iain,Collis, Alan J.,Mould, Roger J.,Rathmell, Richard E.
, p. 2739 - 2746 (2007/10/02)
A number of routes to 2-vinylaziridines are reported.N-Alkylation of a range of 2-benzoyl-3-alkylaziridines with tert-butyl bromoacetate followed by Wittig olefination gave directly a range of 4-phenylpiperidines.The intermediate 2-vinylaziridines rearran
