1733-68-2Relevant academic research and scientific papers
Synthesis, Vibrational Spectra, Mass Spectrum and Crystal Structure of Tri-n-butyltin Diphenylphosphinate (n-Bu)3SnO2PPh2
Shihada, Abdel-Fattah,Weller, Frank
, p. 1343 - 1347 (2007/10/03)
Tri-n-butyltin diphenylphosphinate (n-Bu)3SnO2PPh2 has been synthesized by the reaction of (n-Bu3Sn)2O with Ph2POCl in toluene.An X-ray diffraction study of (n-Bu3)SnO2PPh2 shows that the structure is polymeric and consists of helical chains in which (n-Bu)3Sn groups are linked by O-P-O bridges.The geometry about tin is trigonal bipyramidal, with n-butyl groups in equatorial positions and an axial O-Sn-O angle of 176.2(2) deg.IR and Raman spectra of (n-Bu)3SnO2PPh2 are given and assigned.The mass spectrum is reported and discussed. - Keywords: Crystal Structure, Vibrational Spectra, Mass Spectrum, Tri-n-butyltin Diphenylphosphinate
