173379-20-9Relevant academic research and scientific papers
Versatile iodination of olefins by potassium dichloroiodate(I)
Zefirov,Sereda,Sosonuk,Zyk,Likhomanova
, p. 1359 - 1361 (1995)
The versatile electrophilic iodination of double bonds with potassium dichloroiodate(I) is described. In most examples various β-substituted iodides, particularly vic-iodochlorides were synthesised in excellent yields.
Synthesis and Photochemical Application of Hydrofluoroolefin (HFO) Based Fluoroalkyl Building Block
Varga, Bálint,Tóth, Balázs L.,Béke, Ferenc,Csenki, János T.,Kotschy, András,Novák, Zoltán
supporting information, p. 4925 - 4929 (2021/07/01)
A novel fluoroalkyl iodide was synthesized on multigram scale from refrigerant gas HFO-1234yf as cheap industrial starting material in a simple, solvent-free, and easily scalable process. We demonstrated its applicability in a metal-free photocatalytic ATRA reaction to synthesize valuable fluoroalkylated vinyl iodides and proved the straightforward transformability of the products in cross-coupling chemistry to obtain conjugated systems.
