173427-90-2

Upstream product

• 18922-04-8 6-iodohex-1-ene 
• 123-31-9 hydroquinone 
• 2695-47-8 6-Bromo-1-hexene 
• 821-41-0 5-Hexen-1-ol 

Downstream Products

• 173427-91-3 -6,6'-<1,4-phenylenebis(oxy)>bis-1,2-hexanediol 
• 197968-25-5 1,4-Bis-[(5R,9S)-9-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-diphenyl-silanyloxy)-dec-7-ynyloxy]-benzene 
• 173427-93-5 (2S,6R)-6-(tert-Butyl-diphenyl-silanyloxy)-10-{4-[(5R,9S)-5-(tert-butyl-diphenyl-silanyloxy)-9-hydroxy-dec-7-ynyloxy]-phenoxy}-dec-3-yn-2-ol 
• 197968-19-7 {2R-[2α[2'R*, 5'R*(R*)],5β],[1(S*), 2R*, 11R*]}-3-{2-[(1,1-dimethylethyl)diphenylsilyloxy]-11-hydroxy-11-[octahydro-5'-(1-hydroxyundec-3-ynyl) [2.2'-bifuran]-5-yl]-6-undecen-8-ynyl}-5-methyl-2-(5H)-furanone 
• 173428-01-8 (S)-3-{(2R,11R)-2-(tert-Butyl-diphenyl-silanyloxy)-11-hydroxy-11-[(2R,5R,2'R,5'R)-5'-((R)-1-hydroxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-undecyl}-5-methyl-5H-furan-2-one 
• 197968-24-4 (5R,9S)-9-(tert-Butyl-dimethyl-silanyloxy)-1-{4-[(5R,9S)-9-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-dec-7-ynyloxy]-phenoxy}-dec-7-yn-5-ol 
• 216162-67-3 (S)-3-[(E)-(R)-2-(tert-Butyl-diphenyl-silanyloxy)-7-iodo-hept-6-enyl]-5-methyl-5H-furan-2-one 
• 197968-28-8 (R)-5-(tert-Butyl-diphenyl-silanyloxy)-6-((S)-5-methyl-2-oxo-2,5-dihydro-furan-3-yl)-hexanal 
• 197968-27-7 (S)-3-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-6-hydroxy-hexyl]-5-methyl-5H-furan-2-one 
• 173427-92-4 (+)-{R-[R*(R*)]}-{4-[4-(4-oxiranyl)butoxy]phenoxy}butyloxirane 

Relevant academic research and scientific papers

Synthesis of functionalized copillar[4+1]arenes and rotaxane as heteromultivalent scaffolds

In this study, novel copillar[4+1]arenes were used as central heteromultivalent scaffolds via orthogonal couplings with a series of biologically relevant molecules such as carbohydrates, α-amino acids, biotin and phenylboronic acid. Further modifications by introducing maleimides or cyclooctyne groups provided molecular probes adapted to copper-free click chemistry. An octa-azidated fluorescent rotaxane bearing two distinct ligands was also generated in a fully controlled manner.

Efficient macrocyclization achieved via conformational control using intermolecular noncovalent π-cation/arene interactions

Quinolinium salt 3 is an effective additive that acts as a conformation control element (CCE) to promote macrocyclization to form rigid cyclophanes via olefin metathesis or Glaser-Hay coupling, which do not cyclize in the absence of the additive. The additives are easily synthesized and highly modifiable and have solubility profiles which allow for simple recovery via filtration.

Orientation effects in monodomain nematic liquid crystalline polysiloxane elastomers

A series of monodomain liquid crystalline (LC) elastomers based on a polysiloxane were synthesised. These elastomers were prepared either with one or two cross-linking agents in the presence of a mechanical field. By using the real-time X-ray facility at

Synthesis of acetogenins

A method for the synthesis of bis-tetrahydrofuranyl annonaceous acetogenins, including the natural products and analogs thereof, is provided which proceeds by the Pd-mediated coupling of a bis-tetrahydrofuranyl-subunit comprising a terminal alkyne, with a