173439-74-2Relevant articles and documents
Synthesis of cis-vinyltrimethylstannanes and cis-vinylpinacolboronates in a two-step highly regio and stereoselective process
Mirzayans, Paul Malek,Pouwer, Rebecca H.,Williams, Craig M.,Bernhardt, Paul V.
experimental part, p. 8297 - 8305 (2009/12/24)
A highly efficient two-step regio and stereoselective method for the synthesis of both cis-vinyltrimethylstannanes and cis-vinylpinacolboronates is described. This method takes advantage of the known lithium/tellurium exchange pathway providing a versatil
Hydrozirconation of acetylenic chalcogenides. Synthesis and reactions of zirconated vinyl chalcogenide intermediates
Dabdoub, Miguel J.,Begnini, Mauro L.,Guerrero Jr., Palimecio G.
, p. 2371 - 2400 (2007/10/03)
Acetylenic tellurides react with Cp2Zr(H)Cl in THF at room temperature to give the α-zirconated vinyl telluride intermediates 39, which react with a wide range of electrophiles to give several types of trisubstituted olefins, such as α-halo vin
Total control on the synthesis of regio and stereoisomers of vinylic tellurides.
Dabdoub,Cassol
, p. 12971 - 12982 (2007/10/02)
Methodologies for the total control on the synthesis of E, Z or 1,1-dissubstituted vinylic tellurides are described. Tellurobutadienes bearing the butyltellurium moiety at carbon 2 or at carbon 1 with E or Z configuration at the tellurium containing doubl
