173449-39-3Relevant academic research and scientific papers
Syntheses and Structures of 13-Substituted 1,5,9-Triazatricyclo5,13>tridecanes and Their Copper(II) Chloride Complexes
Koehn, Randolf D.,Seifert, Guido,Kociok-Koehn, Gabriele
, p. 21 - 24 (2007/10/02)
The orthoamides 2a, b (R = Ph and PhCH2) have been prepared by alkylation of the guanidinium salt 4+BPh4- with PhNa and PhCH2Na, respectively.The crystal structures of the two orthoamides have been determined by X-ray crystallography.Their reaction with CuCl2 gives 1:1 complexes.The crystal structure of the complex with 2a shows a square planar geometry around the copper atom with η2-2a and two chlorides and weak interactions to the third nitrogen atom and a C-H bond of 2a in the axial positions. - Keywords: Orthoamides / Trisaminomethanes, tricyclic / Guanidinium cation, alkylation / Copper(II) complexes
