1735-93-9Relevant academic research and scientific papers
FLUORINE-CONTAINING COMPLEX COMPOUND, AND PRODUCTION METHOD FOR FLUORINE-CONTAINING ORGANIC COMPOUND EMPLOYING SAME
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Paragraph 0413; 0414; 0415, (2016/08/17)
An object of the present invention is to enable the synthesis of various fluorine-containing compounds having an organic group at both terminals of their tetrafluoroethylene structure (—CF2—CF2—). The present invention provides a flu
Fluoroalkylcopper(I) complexes generated by the carbocupration of tetrafluoroethylene: Construction of a tetrafluoroethylene-bridging structure
Saijo, Hiroki,Ohashi, Masato,Ogoshi, Sensuke
, p. 15158 - 15161 (2014/12/11)
We report a copper-mediated synthesis of a variety of 1,2-difunctionalized-1,1,2,2-tetrafluoroethylene derivatives via the carbocupration of tetrafluoroethylene. The key synthetic intermediates, 2-aryl-1,1,2,2-tetrafluoroethylcopper complexes, can be easily prepared, stored, and used as fluoroalkylation reagents. The molecular structure was unambiguously determined by X-ray crystallography and NMR analysis. We applied this method to the short-step synthesis of a liquid-crystalline compound bearing a tetrafluoroethylene-bridging structure.
