173537-17-2Relevant academic research and scientific papers
Pd-catalyzed substitution of the oh group of nonderivatized allylic alcohols by phenols
Rukkijakan, Thanya,Akkarasamiyo, Sunisa,Sawadjoon, Supaporn,Samec, Joseph S. M.
, p. 4099 - 4104 (2018)
Nonactivated phenols have been employed as nucleophiles in the allylation of nonderivatized allylic alcohols to generate allylated phenolic ethers with water as the only byproduct. A Pd[BiPhePhos] catalyst was found to be reactive to give the O-allylated phenols in good to excellent yields in the presence of molecular sieves. The reactions are chemoselective in which the kinetically favored O-allylated products are formed exclusively over the thermodynamically favored C-allylated products.
Pyridine hydrobromide perbromide mediated regioselective heterocyclization of ortho-cyclohexenyl phenols
Majumdar, Krishna C.,Kundu, Anup K.
, p. 1727 - 1732 (2007/10/02)
A number of 3,4-benzo-9-bromo-2-oxabicyclononanes (9a-h) are synthesized in almost quantitative yields by regioselective heterocyclization of ortho-cyclohexenyl phenols (8a-h).The structures of 3,4-benzo-9-bromo-2-oxabicyclononane 9 have bee
