17357-25-4

Basic information

• Product Name: Ethanone, 2,2-dibromo-1-(2-furanyl)-
• CAS NO: 17357-25-4
• Molecular Formula: C6H4Br2O2
• Mol File: 17357-25-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 2,2-dibromo-1-(2-furanyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2,2-dibromo-1-(2-furanyl)-(17357-25-4)
• EPA Substance Registry System: Ethanone, 2,2-dibromo-1-(2-furanyl)-(17357-25-4)

Safety Data

• Hazardous Substances Data: 17357-25-4(Hazardous Substances Data)

Upstream product

• 1192-62-7 1-(2-furyl)-1-ethanone 
• 62889-08-1 1-(2-furyl)-1-(trimethylsilyloxy)ethylene 

Relevant articles and documents

TMS·OTf-Catalyzed α-bromination of carbonyl compounds by N-bromosuccinimide

Various carbonyl compounds undergo α-bromination reaction under a mild and practical condition utilizing N-bromosuccinimide (NBS), catalyzed by trimethylsilyl trifluoromethanesulfonate (TMS·OTf). This method is also effective for the side-chain bromination of heteroaromatic carbonyl compounds without the ring brominations.

MAGNESIUM CHLORIDE DIRECTED ALDOL AND BROMINATION OF 2-ACETYLFURAN

Reaction of 2-acetylfuran with diisopropylethylamine and magnesium chloride followed by bromination gave 1,3-difuryl-3-hydroxy-1-butanone and 1,3-difuryl-4-bromo-3-hydroxy-1-butanone.Under similar conditions 2-acetylthiophene failed to react.