17364-14-6

Basic information

• Product Name: d-Glucose, 1-(dihydrogen phosphate), sodium salt
• Synonyms: d-Glucose, 1-(dihydrogen phosphate), sodium salt;glucose-1-phosphate sodium salt
• CAS NO: 17364-14-6
• Molecular Formula: C₆H₁₁O₉P*2Na
• Molecular Weight: 298.117011
• EINECS: 241-395-1
• Mol File: 17364-14-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: d-Glucose, 1-(dihydrogen phosphate), sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: d-Glucose, 1-(dihydrogen phosphate), sodium salt(17364-14-6)
• EPA Substance Registry System: d-Glucose, 1-(dihydrogen phosphate), sodium salt(17364-14-6)

Safety Data

• Hazardous Substances Data: 17364-14-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H13O9P.Na/c7-1-2-3(8)4(9)5(10)6(14-2)15-16(11,12)13;/h2-10H,1H2,(H2,11,12,13);/q;+1/p-1/rC6H12NaO9P/c7-16-17(12,13)15-6-5(11)4(10)3(9)2(1-8)14-6/h2-6,8-11H,1H2,(H,12,13)

Upstream product

• 374726-35-9 dibenzyl 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl phosphate 
• 149717-36-2 dibenzyl 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl phosphite 
• 3947-62-4 2,3,4,5-tetra-O-acetyl-D-glucopyranose 
• 83-87-4 D-glucose pentaacetate 

Relevant articles and documents

Synthesis and use of glycosyl phosphites: An effective route to glycosyl phosphates, sugar nucleotides, and glycosides

An efficient and convenient synthetic route to glycosyl phosphites and phosphates has been developed that uses dibenzyl N,N-diethylphosphoramidite as a phosphitylating reagent. Glycosyl phosphites and phosphates of 2-acetamido-2-deoxy-D-galactose (GalNAc) (29), 2-acetamido-2-deoxy-D-glucose (GlcNAc) (30), D-galactose (Gal) (31), D-glucose (Glc) (32), D-mannose (Man) (33), L-rhamnose (Rha) (34), L-fucose (Fuc) (35), and N-acetylneuraminic acid (NeuAc) (41) were prepared by this procedure. Compounds 29 and 30 were obtained as α anomers exclusively, whereas compounds 31, 32, and 41 were obtained as β anomers, and compounds 33 and 34, as α anomers, predominately. The phosphates are useful for the synthesis of sugar nucleotides, and the phosphites are effective glycosylation reagents.