173673-32-0Relevant academic research and scientific papers
A new source of nitrogen centered radicals
Callier-Dublanchet, Anne-Claude,Quiclet-Sire, Beatrice,Zard, Samir Z.
, p. 8791 - 8794 (2007/10/02)
Exposure of thiocarbazone derivatives 6b-10b, 11c-13c, and 14a-15a to tributylstannane in the presence of AIBN leads to various nitrogen centered radicals which are easily captured by an internal olefin.
Iminyl Radicals: Part I. Generation and Intramolecular Capture by an Olefin.
Boivin, Jean,Fouquet, Eric,Zard, Samir Z.
, p. 1745 - 1756 (2007/10/02)
Slow addition of tributylstannane to sulphenylimines 2 give the corresponding Δ1-pyrrolenines 5 by an intramolecular addition of the intermediate iminyl radical, a process which can be easily coupled to an intermolecular addition to an electrophilic olefin.
CYCLISATION OF IMINE RADICALS DERIVED FROM SULPHENYLIMINES: A SIMPLE ACCESS TO Δ1-PYRROLINES
Boivin, Jean,Fouquet, Eric,Zard, Samir Z.
, p. 85 - 88 (2007/10/02)
Treatment of various sulphenylimines containing a γ,δ-double bond with tri-n-butylstannane affords the corresponding pyrroline derivatives in good yield.
