17404-29-4Relevant academic research and scientific papers
Branch-Selective Hydroarylation: Iodoarene-Olefin Cross-Coupling
Green, Samantha A.,Matos, Jeishla L. M.,Yagi, Akiko,Shenvi, Ryan A.
supporting information, p. 12779 - 12782 (2016/10/13)
A combination of cobalt and nickel catalytic cycles enables a highly branch-selective (Markovnikov) olefin hydroarylation. Radical cyclization and ring scission experiments are consistent with hydrogen atom transfer (HAT) generation of a carbon-centered radical that leads to engagement of a nickel cycle.
Zr-Catalyzed Electrophilic Carbomagnesation of Aryl Olefins. Mechanism-Based Control of Zr-Mg Ligand Exchange
De Armas, Judith,Hoveyda, Amir H.
, p. 2097 - 2100 (2007/10/03)
(Formula Presented) The first examples of efficient electrophilic Zr-catalyzed carbomagnesations are disclosed, where in contrast to previous catalytic carbomagnesations the alkyl moiety of the electrophile is transferred (vs that of the Grignard reagent)
