174063-70-8

Basic information

• Product Name: 3-Oxepanol,7-methyl-2-(1-methylethyl)-,(2alpha,3bta,7bta)-(9CI)
• Synonyms: 3-Oxepanol,7-methyl-2-(1-methylethyl)-,(2alpha,3bta,7bta)-(9CI)
• CAS NO: 174063-70-8
• Molecular Formula: C10H20O2
• Molecular Weight: 172.2646
• Product Categories: ISOPROPYL
• Mol File: 174063-70-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Oxepanol,7-methyl-2-(1-methylethyl)-,(2alpha,3bta,7bta)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxepanol,7-methyl-2-(1-methylethyl)-,(2alpha,3bta,7bta)-(9CI)(174063-70-8)
• EPA Substance Registry System: 3-Oxepanol,7-methyl-2-(1-methylethyl)-,(2alpha,3bta,7bta)-(9CI)(174063-70-8)

Safety Data

• Hazardous Substances Data: 174063-70-8(Hazardous Substances Data)

Upstream product

• 133909-64-5 5-((2S,3S)-3-Isopropyl-oxiranyl)-pentan-2-one 
• 173963-17-2 2,5,5-Trimethyl-2-(6-methyl-hept-4-ynyl)-[1,3]dioxane 
• 65727-42-6 8-methyl-non-6t-en-2-one 
• 598-23-2 3-methyl-but-1-yne 
• 88128-58-9 2-methyl-2-(3-bromopropyl)-5,5-dimethyl-1,3-dioxane 

Relevant articles and documents

Oxepanes from an unusual acetal cleavage of 6,8-dioxabicyclo[3.2.1]octanes

On treatment with BF3 · OEt2 and TMSCN, epoxy ketone 1 cyclized to the bicyclic acetal 2, which then cleaved to give primarily the oxepane 5 as a single stereoisomer. Reductive decyanation of 5 led to the oxepane 7, a structural unit present in the brevetoxin family of natural products. The scope and limitations of this reaction sequence were investigated.