174094-75-8

Basic information

• Product Name: K⁽¹⁺⁾*Ru((CH₃CO)2CNO)(C₁₄H₁₀NO₂)2^(1-)=K[RuC₃₃H₂₆N₃O₇]
• CAS NO: 174094-75-8
• Molecular Weight: 716.754
• Mol File: 174094-75-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: K⁽¹⁺⁾*Ru((CH₃CO)2CNO)(C₁₄H₁₀NO₂)2^(1-)=K[RuC₃₃H₂₆N₃O₇](CAS DataBase Reference)
• NIST Chemistry Reference: K⁽¹⁺⁾*Ru((CH₃CO)2CNO)(C₁₄H₁₀NO₂)2^(1-)=K[RuC₃₃H₂₆N₃O₇](174094-75-8)
• EPA Substance Registry System: K⁽¹⁺⁾*Ru((CH₃CO)2CNO)(C₁₄H₁₀NO₂)2^(1-)=K[RuC₃₃H₂₆N₃O₇](174094-75-8)

Safety Data

• Hazardous Substances Data: 174094-75-8(Hazardous Substances Data)

Upstream product

• 174094-71-4 RuC₂₈H₂₀N₃O₅Cl 
• 123-54-6 acetylacetone 

Relevant articles and documents

Synthesis, characterization and reactivity studies of some electrophilic mono- and binuclear nitrosyls of ruthenium(II) containing ketoximates

The reaction of [RuX2(HL)(L)] (2) [X = Cl or Br; HL (1) = PhC(O)C( = NOH)Ph (HL1) or PhC(O)C(=NOH)Me (HL2)] with BuONO affords mononuclear [RuX(NO)L21] (3) or binuclear [RuX2(NO)L2]2 (4) nitrosyls depending on L; 3 and 4 are also obtainable by reacting 2 with NaNO2 in the presence of hydrochloric acid. Molecular weight determinations are in full consonance with mono- and binuclear formulations. Both 3 and 4 are electroactive and reductions characteristic of mono- and binuclear compositions are observable on the negative side of SCE. They react smoothly with acetylacetone (acacH) in presence of K2CO3 affording K[Ru(acamo)L21] (6) and K[Ru(acac)(acamo)L2] (7) [acamo is deprotonated CH3C(= O)C(=NOH)[C(=O)CH3] respectively.