174148-64-2

Upstream product

• 160256-44-0 1-Benzyloxymethyl-3-[1-((3aR,4S,6R,7aR)-1-benzyloxymethyl-4-hydroxymethyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-yl)-1H-indol-3-yl]-4-(1H-indol-3-yl)-pyrrole-2,5-dione 

Downstream Products

• 174148-65-3 3-{1-Benzyloxymethyl-4-[1-((3aR,4R,6R,7aR)-1-benzyloxymethyl-4-iodomethyl-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-yl)-1H-indol-3-yl]-2,5-dioxo-2,5-dihydro-1H-pyrrol-3-yl}-indole-1-carboxylic acid benzyl ester 
• 174148-66-4 3-{1-Benzyloxymethyl-4-[1-((3aR,6R,7aR)-1-benzyloxymethyl-4-methylene-2-oxo-hexahydro-pyrano[4,3-d]oxazol-6-yl)-1H-indol-3-yl]-2,5-dioxo-2,5-dihydro-1H-pyrrol-3-yl}-indole-1-carboxylic acid benzyl ester 
• 174148-70-0 C₄₃H₃₆N₄O₆ 

Relevant academic research and scientific papers

Staurosporine and ent-staurosporine: The first total syntheses, prospects for a regioselective approach, and activity profiles

The total syntheses of staurosporine and ent-staurosporine have been achieved. Both glycosidic bonds were built from glycal precursors. The first was constructed by intermolecular coupling of an indole anion with a 1,2-anhydrosugar derived from an endo-glycal by direct epoxidation. The second bond was assembled from an exo-glycal by intramolecular iodoglycosylation.