17420-29-0

Usage

InChI:InChI=1/C17H29P/c1-15(2,3)12-10-13(16(4,5)6)18-14(11-12)17(7,8)9/h10-11H,1-9H3

Upstream product

• 47036-33-9 2,4,6-tri-tert-butyl-1-oxo-1,2-dihydro-1λ⁵-phosphinin-1-ol 
• 37912-85-9 2,4,6-Tri-tert-butyl-1,1-dimethoxy-λ⁵-phosphinin 
• 62496-95-1 1,1,4-Tribromo-2,4,6-tri-tert-butyl-1,4-dihydro-1λ⁵-phosphinine 

Downstream Products

• 57604-56-5 2,4,6-tri-tert-butyl-1-methoxy-1-(2-methyl-4-nitro-phenyl)-1λ⁵-phosphinine 
• 1460-02-2 1,3,5-Tri-tert-butylbenzene 
• 3975-76-6 chloro-2,4,6-tri-tert-butylbenzene 
• 37912-85-9 2,4,6-Tri-tert-butyl-1,1-dimethoxy-λ⁵-phosphinin 

Relevant academic research and scientific papers

λ3-Phosphinines with a Functional Group at C-4

Hitherto unknown derivatives of λ3-phosphinines with a functional substituent at C-4, such as CN (10), CO2CH3 (11), or CH2CN (5), as well as 4,4'-methylenebis(2,6-diphenyl)-λ3-phosphinine) (6) are prepared under mild conditions by reductive elimination of both methoxyl groups from the phosphorus atom of the 4-substituted 1,1-dimethoxy-2,6-diphenyl-λ5-phosphinines (2, 7).The new λ3-phosphinines are crystalline and except for 6 air-stable compounds, whose analytical and spectroscopic data are reported in the Tables 1 and 2.

Phosphabenzene-Nickel Complexes

The reaction of (COD)2Ni (1) or (COT)2Ni2 (11) with the 2,4,6-trisubstituted phosphabenzene derivatives 2 or 3 results in displacement of one COD or COT molecule to give the cycloolefinbis(phosphabenzene)-nickel complexes 6, 7 or 12, respectively.CDTNi (8