174303-49-2Relevant articles and documents
Ruthenium(II)-Catalyzed Microwave-Promoted Multiple C-H Activation in Synthesis of Hexa(heteroaryl)benzenes in Water
Drev, Miha,Gro?elj, Uro?,Ledinek, Bine,Perdih, Franc,Svete, Jurij,?tefane, Bogdan,Po?gan, Franc
supporting information, p. 5268 - 5273 (2018/09/13)
A series of hexa(heteroaryl)benzenes were synthesized by the Ru(II)-carboxylate-catalyzed multiple C-H activation of benzenes carrying pyridyl, pyrimidyl, or pyrazolyl directing groups using N-heteroaryl bromides as coupling partners. The reactions procee
Cobalt-catalyzed cross-coupling between in situ prepared arylzinc halides and 2-chloropyrimidine or 2-chloropyrazine
Begouin, Jeanne-Marie,Gosmini, Corinne
supporting information; experimental part, p. 3221 - 3224 (2009/09/26)
A cobalt-catalyzed cross-coupling of aryl halides with 2-chloropyrimidines or 2-chloropyrazines is reported in satisfactory to high yields. The key step of this procedure is the formation of aromatic organozinc reagents and their coupling with 2-chlorodia
Synthesis of oligo(diazaphenyls). Tailor-made fluorescent heteroaromatics and pathways to nanostructures
Gompper, Rudolf,Mair, Hans-Jürgen,Polborn, Kurt
, p. 696 - 718 (2007/10/03)
Oligoaza derivatives of biphenyl, terphenyl, quaterphenyl, quinquephenyl, sexiphenyl, septiphenyl, octiphenyl, noviphenyl, deciphenyl and dodeciphenyl and poly(pyrimidinylenephenylene) can be synthesized from readily accessible vinamidinium salts and amidines or N,N,N'- tris(trimethylsilyl)amidines. The fluorescence of these systems can be tuned over a wide spectral range by varying number and positions of N atoms. Oligo(diazaphenyls) are thermally and photochemically stable, are easier to reduce than oligopheny]s, can be dissolved at any rate in strong acids and show strong blue fluorescence in solution as well as in the solid state.