174360-08-8

Basic information

• Product Name: Carbamic acid, [2-(methylthio)ethyl]-, 1,1-dimethylethyl ester (9CI)
• Synonyms: Carbamic acid, [2-(methylthio)ethyl]-, 1,1-dimethylethyl ester (9CI);CarbaMic acid, [2-(Methylthio)ethyl]-, 1,1-diMethylethyl ester;tert-Butyl [2-(Methylthio)ethyl]carbaMate, 97%
• CAS NO: 174360-08-8
• Molecular Formula: C₈H₁₇NO₂S
• Molecular Weight: 191.29108
• Product Categories: N-BOC
• Mol File: 174360-08-8.mol
• Article Data: 14

Chemical Properties

• Appearance: Colorless to yellow/Liquid
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Carbamic acid, [2-(methylthio)ethyl]-, 1,1-dimethylethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [2-(methylthio)ethyl]-, 1,1-dimethylethyl ester (9CI)(174360-08-8)
• EPA Substance Registry System: Carbamic acid, [2-(methylthio)ethyl]-, 1,1-dimethylethyl ester (9CI)(174360-08-8)

Safety Data

• Hazardous Substances Data: 174360-08-8(Hazardous Substances Data)

Usage

Uses

N-Boc-2-(methylthio)ethylamine is used as a reagent in the synthesis of anthranilic diamide insecticides and new glycopeptidomimetics based on N-substituted oligoglycines bearing N-linked lactoside side chains.

Upstream product

• 67385-09-5 2-[(tert-butoxycarbonyl)amino]-1-ethanethiol 
• 74-88-4 methyl iodide 
• 18542-42-2 (2-aminoethyl)methylsulfide 
• 24424-99-5 di-tert-butyl dicarbonate 
• 96628-67-0 2-(tert-butoxycarbonylamino)ethyl methanesulfonate 
• 5188-07-8 sodium thiomethoxide 
• 6950-53-4 2‐(methylsulfanyl)ethan‐1‐amine hydrochloride 
• 36016-38-3 tert-Butyl N-hydroxycarbamate 
• 71999-74-1 tert-butyl N-(2-chloroethyl)carbamate 
• 34619-03-9 tert-butyldicarbonate 

Downstream Products

• 18542-42-2 (2-aminoethyl)methylsulfide 
• 6950-53-4 2‐(methylsulfanyl)ethan‐1‐amine hydrochloride 
• 21485-78-9 N-methyl-2-(methylthio)ethylamine 

Relevant articles and documents

Novel anthranilic diamide insecticides: Design, synthesis, and insecticidal evaluation

Three series of new anthranilic diamide derivatives containing sulfide, N-cyanomethylsulfilimine, and N-cyanomethylsulfoximine groups were designed and synthesized by coupling the active substructures of anthranilic diamides and sulfoxaflor. The structures of the synthesized compounds were confirmed by infrared spectroscopy, 1H and 13C NMR, and elemental analysis. Several unique structural characteristics were revealed via the crystal structure analysis of compound N-(2-(2-methyl-2-(methylthio)propylcarbamoyl)-4-chloro-6-methylphenyl)-3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxamide 16e. Bioassay results indicated that most of the synthesized compounds showed superior insecticidal activities against Mythimna separata and Plutella xylostella when compared with the positive control cyantraniliprole. In particular, N-(2-(2-methyl-2-(N-cyanomethylsulfideimino)propylcarbamoyl)-4-chloro-6-methylphenyl)-3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxamide 17e showed excellent insecticidal activity against Mythimna separata, with a mortality rate of 100% at a concentration of 1μgmL-1. These results indicated that sulfide, N-cyanomethylsulfilimine, and N-cyanomethylsulfoximine moieties, as important active substructures, could improve or maintain the activity of the anthranilic diamide and promote novel pesticide development.

5 - ALA Conjugate preparation method and application thereof

The invention provides 5 - ALA conjugate preparation method and application thereof, and the preparation method comprises 5 - ((2 - aminoethyl) amino) -4 -oxopentanoate synthesis and 5 - ALA conjugate synthesis steps, and the obtained 5 - ALA conjugate is

A pharmaceutically acceptable salt and its preparation and use

The invention relates to a pharmaceutical salt, and a preparation method and application thereof, in particular to an acid addition salt of N-(4-(3-fluorobenzyl)-3-chlorphenyl)-6-(5-((2-(methylsulfinyl)ethylamino)methyl)-2-furyl)-quinazoline-4-amine shown