174470-24-7Relevant academic research and scientific papers
Methylchlorooligosilanes as products of the basecatalysed disproportionation of various methylchlorodisilanes
Herzog,Richter,Brendler,Roewer
, p. 221 - 228 (2007/10/03)
The methylchlorodisilanes SiCl2Me-SiCl2Me (1), SiCl2Me-SiClMe2 (2) and SiClMe2-SiClMe2 (3) disproportionate in the presence of a basic catalyst into methylchloromonosilanes and various methylchlorooligosilanes. Oligosilanes involving up to seven silicon atoms were identified by means of 29Si-, 13C-1H-NMR and GC-MS measurements. Formation of methylchlorooligosilanes is thought to take place via silylene intermediates.
