17448-52-1Relevant academic research and scientific papers
Cu-catalyzed enantioselective conjugate addition of alkylzincs to cyclic nitroalkenes: Catalytic asymmetric synthesis of cyclic α-substituted ketones
Luchaco-Cullis, Courtney A.,Hoveyda, Amir H.
, p. 8192 - 8193 (2007/10/03)
An efficient and highly enantioselective (≥92% ee) catalytic method for conjugate addition of alkylzinc reagents to cyclic nitroalkenes is reported. Reactions are promoted in the presence of 0.5-5 mol % (CuOTf)2·C6H6 and 1
Direct and Efficient Preparation of gem-Chloronitro Compounds or Nitro Compounds from gem-Bromonitro Compounds
Amrollah-Madjdabadi, A.,Beugelmans, R.,Lechevallier, A.
, p. 826 - 828 (2007/10/02)
Sodiumethanethiolate in methanol is an efficient reducing agent for gem-bromonitro compounds; treatment of the resultant nitronates with a protic acid or with N-chlorosuccinimide gives high yields of the corresponding nitro or gem-chloronitro compounds, respectively.
