174591-33-4

Basic information

• Product Name: (1S,2S,3R)-3-<(4S)-4-(2,2-dimethyl-1,3-dioxolo)>-2-spiro<4'<2'-phenyl-5'(4'H)-oxazolone>>-1-trimethylsilyloxy-5-cyclohexene
• Synonyms: (1S,2S,3R)-3-<(4S)-4-(2,2-dimethyl-1,3-dioxolo)>-2-spiro<4'<2'-phenyl-5'(4'H)-oxazolone>>-1-trimethylsilyloxy-5-cyclohexene
• CAS NO: 174591-33-4
• Molecular Weight: 415.561
• Mol File: 174591-33-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2S,3R)-3-<(4S)-4-(2,2-dimethyl-1,3-dioxolo)>-2-spiro<4'<2'-phenyl-5'(4'H)-oxazolone>>-1-trimethylsilyloxy-5-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,3R)-3-<(4S)-4-(2,2-dimethyl-1,3-dioxolo)>-2-spiro<4'<2'-phenyl-5'(4'H)-oxazolone>>-1-trimethylsilyloxy-5-cyclohexene(174591-33-4)
• EPA Substance Registry System: (1S,2S,3R)-3-<(4S)-4-(2,2-dimethyl-1,3-dioxolo)>-2-spiro<4'<2'-phenyl-5'(4'H)-oxazolone>>-1-trimethylsilyloxy-5-cyclohexene(174591-33-4)

Safety Data

• Hazardous Substances Data: 174591-33-4(Hazardous Substances Data)

Upstream product

• 63383-46-0 1-(trimethylsiloxy)-1,3-butadiene 
• 154663-54-4 (Z)-4-<(S)-2,2-dimethyl-1,3-dioxolan-4-ylmethylidene>-2-phenyl-1,3-oxazol-5(4H)-one 

Relevant articles and documents

High-pressure and thermally induced asymmetric Diels-Alder cycloadditions of heterosubstituted dienes to homochiral α,β-didehydro amino acid derivatives

An amino pentenoate and an unsaturated oxazolone have shown to be suitable homochiral dienophiles to be reacted with electron-rich heterosubstituted dienes. High-pressure and thermal activation have been studied for these cycloadditions. The adducts obtained are polyfunctional building blocks useful for the synthesis of enantiopure cyclohexane amino acids and related products.