174682-12-3

Basic information

• Product Name: Ethanone, 1-(2-hydroxy-1,2-dimethyl-4-methylenecyclopentyl)-, trans- (9CI)
• Synonyms: Ethanone, 1-(2-hydroxy-1,2-dimethyl-4-methylenecyclopentyl)-, trans- (9CI)
• CAS NO: 174682-12-3
• Molecular Formula: C10H16O2
• Molecular Weight: 168.23284
• Product Categories: ACETYLGROUP
• Mol File: 174682-12-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(2-hydroxy-1,2-dimethyl-4-methylenecyclopentyl)-, trans- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(2-hydroxy-1,2-dimethyl-4-methylenecyclopentyl)-, trans- (9CI)(174682-12-3)
• EPA Substance Registry System: Ethanone, 1-(2-hydroxy-1,2-dimethyl-4-methylenecyclopentyl)-, trans- (9CI)(174682-12-3)

Safety Data

• Hazardous Substances Data: 174682-12-3(Hazardous Substances Data)

Upstream product

• 196715-62-5 Acetic acid 4-acetyl-4-methyl-2-methylene-5-oxo-hexyl ester 
• 119253-86-0 3-acetyl-3-methyl-6-(trimethylsilyl)methyl-6-hepten-2-one 

Relevant articles and documents

A sequence of palladium-catalyzed borylation of allyl acetates with bis(pinacolato)diboron and intramolecular allylboration for the cyclization of oxo-2-alkenyl acetates

The cross-coupling reaction of bis(pinacolato)diboron with oxo-2-alkenyl acetates in toluene at 50 °C in the presence of Pd(dba)2/2 AsPh3 (3 mol%) to give allylboronates was followed by the intramolecular allylboration at 100 °C. The sequence provided cyclic homoallyl alcohols in high yields.