174690-80-3

Basic information

• Product Name: C₄₅H₄₈N₂O₈
• CAS NO: 174690-80-3
• Molecular Weight: 744.885
• Mol File: 174690-80-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₄₅H₄₈N₂O₈(CAS DataBase Reference)
• NIST Chemistry Reference: C₄₅H₄₈N₂O₈(174690-80-3)
• EPA Substance Registry System: C₄₅H₄₈N₂O₈(174690-80-3)

Safety Data

• Hazardous Substances Data: 174690-80-3(Hazardous Substances Data)

Upstream product

• 144542-72-3 (3S,5S,6R)-4-(tert-butyloxycarbonyl)-5,6-diphenyl-3-(3'-butenyl)-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one 
• 112741-49-8 tert-butyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate 
• 144542-73-4 (3S,5S,6R)-4-(tert-butoxycarbonyl)-5,6-diphenyl-3-(2'-carbonylethyl)-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one 

Relevant articles and documents

Asymmetric syntheses of (2S,3S,6S)-, (2S,3S,6R)-, and (2R,3R,6S)-2,3-methano-2,6-diaminopimelic acids. Studies directed to the design of novel substrate-based inhibitors of L,L-diaminopimelate epimerase

The asymmetric syntheses of (2S,3S,6S)-, (2S,3S,6R)-, and (2R,3R,6S)-2,3-methano-2,6-diaminopimelic acids (7a-c) is described. The synthesis features phosphonate coupling of 13 and 14 to form the corresponding E-olefins which are subsequently cyclopropanated and deprotected under dissolving metal conditions.