174712-74-4

Basic information

• Product Name: Ethanone, 1-[4-(hydroxymethyl)-2-cyclobuten-1-yl]-, cis- (9CI)
• Synonyms: Ethanone, 1-[4-(hydroxymethyl)-2-cyclobuten-1-yl]-, cis- (9CI)
• CAS NO: 174712-74-4
• Molecular Formula: C7H10O2
• Molecular Weight: 126.1531
• Product Categories: ACETYLGROUP
• Mol File: 174712-74-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-[4-(hydroxymethyl)-2-cyclobuten-1-yl]-, cis- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[4-(hydroxymethyl)-2-cyclobuten-1-yl]-, cis- (9CI)(174712-74-4)
• EPA Substance Registry System: Ethanone, 1-[4-(hydroxymethyl)-2-cyclobuten-1-yl]-, cis- (9CI)(174712-74-4)

Safety Data

• Hazardous Substances Data: 174712-74-4(Hazardous Substances Data)

Upstream product

• 114728-58-4 cis-3-cyclobutene-1,2-dicarboxylic acid monomethyl ester 
• 135359-12-5 methyl cis-4-(chlorocarbonyl)-2-cyclobutene-1-carboxylate 
• 102299-04-7 cis-4-<<(4-methoxyphenyl)methoxy>methyl>-2-cyclobutene-1-methanol 
• 27652-29-5 cis-Cyclobut-1-en-3,4-dicarbonsaeure 
• 77774-01-7 (1R,4S)-(4-hydroxymethylcyclobut-2-enyl)methanol 
• 10374-07-9 cyclobut-3-ene-1,2-dicarboxylic acid anhydride 

Relevant articles and documents

The preparation and electrocyclic ring-opening of cyclobutenes: Stereocontrolled approaches to substituted conjugated dienes and trienes

Thermal electrocyclic ring-opening of 4-alkyl-2-cyclobutene-1-carbaldehydes occurs at low temperature to give (2Z,4E)-alkadienals exclusively, and the process is exploited in transforming cis-3-cyclobutene-1,2-dimethanol 1 into a variety of naturally occurring 1,3,5-alkatrienes and 2,4-decadienoates. Desymmetrisation of 1 with Pseudomonas fluorescens lipase gives access to both enantiomers of 3-oxabicyclo[3.2.0]hept-6-en-2-one 4, for use in stereocontrolled routes to 6-oxygenated (2Z,4E)-alkadienals.