174714-42-2

Basic information

• Product Name: ethyl 2-fluoro-3-oxo-3-(m-bromophenyl)propionate
• Synonyms: ethyl 2-fluoro-3-oxo-3-(m-bromophenyl)propionate
• CAS NO: 174714-42-2
• Molecular Weight: 289.101
• Mol File: 174714-42-2.mol

Chemical Properties

• CAS DataBase Reference: ethyl 2-fluoro-3-oxo-3-(m-bromophenyl)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-fluoro-3-oxo-3-(m-bromophenyl)propionate(174714-42-2)
• EPA Substance Registry System: ethyl 2-fluoro-3-oxo-3-(m-bromophenyl)propionate(174714-42-2)

Safety Data

• Hazardous Substances Data: 174714-42-2(Hazardous Substances Data)

Upstream product

• 1711-09-7 3-bromobenzoyl chloride 

Downstream Products

• 1301669-29-3 C₂₄H₂₇BrFNO₅ 
• 1179476-75-5 C₂₁H₂₈BrFN₂O₇ 

Relevant articles and documents

Acylation of diethyl (ethoxycarbonyl)fluoromethylphosphonate using magnesium chloride-triethylamine: A facile synthesis of α-fluoro β-keto esters

A facile synthesis of α-fluoro β-keto esters, via diacylation reaction of diethyl (ethoxycarbonyl)fluoromethylphosphonate with aromatic carboxylic acid chlorides in the presence of magnesium chloride-triethylamine followed by deacylation, is described.

Acylation of α-fluorophosphonoacetate derivatives using magnesium chloride-triethylamine

Acylation of α-fluorophosphonoacetate derivatives in the presence of magnesium chloride-triethylamine has been described. Acylations of triethyl α-fluorophosphonoacetate 1 and diethyl α-fluorophosphonoacetic acid 7 were proceeded under mild conditions to provide α-fluoro-β-keto esters 3 and α- fluoro-β-keto phosphonates 9, respectively, in high yields.