174742-77-9

Basic information

• Product Name: (C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)]BF₄
• CAS NO: 174742-77-9
• Molecular Weight: 760.031
• Mol File: 174742-77-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)]BF₄(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)]BF₄(174742-77-9)
• EPA Substance Registry System: (C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)2(C₆H₅)2PCCH(Co₂(CO)6)]BF₄(174742-77-9)

Safety Data

• Hazardous Substances Data: 174742-77-9(Hazardous Substances Data)

Upstream product

• 162194-59-4 [(η(5)-C5H5)Fe(CO)2(Ph2PC.tplbond.CH)][BF4] 

Relevant articles and documents

Reactions of cationic iron P-coordinated (diphenylphosphino) alkynes with dicobalt octacarbonyl

Reaction of the P-coordinated transition metal complexes [(Fp)Ph2PC≡CR][BF4] (R = H, CH3, Ph, p-tolyl; Fp = CpFe(CO)2) with cobalt octacarbonyl at room temperature affords the cationic heterometallic complexes [(Fp)Ph2PC≡CR{Co2(CO)6}][BF4] (1-4) in high yields. A single-crystal X-ray structural analysis of 3 showed that the hexacarbonyldicobalt fragment is π-bonded to the alkynyl group of the P-coordinated (diphenylphosphino)alkyne without significant interaction between the iron and cobalt fragments. Spectroscopic data for 1-4 and structural data for 3 suggest that the positive charge is mainly located on the iron fragment.