174777-58-3

Upstream product

• 41355-50-4 2,3,4,6-tetra-O-acetyl-D-glucosyl-1-amine 
• 93173-26-3 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranosyl isothiocyanate 
• 604-69-3 β-D-glucose pentaacetate 
• 20379-61-7 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl azide 
• 13992-25-1 1-azido-1-deoxy-β-D-glucopyranoside tetraacetate 

Downstream Products

• 174777-59-4 1-((2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yl)-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-thiourea 

Relevant academic research and scientific papers

Synthesis of a tetrahydropyrano[2,3-d]oxazole analogue of trehazolin

Tetrahydropyrano[2,3-d]oxazole 6 as an analogue of trehazolin was synthesized from compound 3, which is a protected 1,3-bis(β-D-glucopyranosyl)thiourea. In contrast, compound 10, a protected 1,3-bis(α-D-glucopyranosyl)thiourea, and 15, a mixed species having one α-D-glucopyranosyl group and one β-D-glucopyranosyl group, did not yield the corresponding pyranooxazolines as anticipated, giving instead, respectively, a furo[2,3-d]oxazole 14 and a complex mixture of unidentified products.