174824-73-8Relevant articles and documents
2-(Trifluoroacetyl)imidazoles, 2-trifluoroacetyl-1,3-thiazoles, and 2-trifluoroacetyl-1,3-oxazoles
Khodakovskiy, Pavel V.,Volochnyuk, Dmitriy M.,Panov, Dmitriy M.,Pervak, Igor I.,Zarudnitskii, Evgenij V.,Shishkin, Oleg V.,Yurchenko, Aleksandr A.,Shivanyuk, Alexander,Tolmachev, Andrey A.
, p. 948 - 956 (2008/09/21)
A facile method of trifluoroacylation of imidazoles, 1,3-thiazoles, and 1,3-oxazoles with trifluoroacetic anhydride resulted in a set of heterocyclic trifluoromethyl-containing ketones. Unlike common ketones, these compounds form stable hydrates and enter into noncatalytic ene reactions with terminal olefins affording the corresponding allyl alcohols. Georg Thieme Verlag Stuttgart.